Arthur D. Storke Memorial Professor
Peter B. Kelemen
Arthur D. Storke Memorial Professor
Earth and Environmental Sciences
61 Route 9W - PO Box 1000
Recently, I have added mineral carbonation and hydration in peridotite and mafic rocks to my research program. This is a reactive transport problem, very similar to the work I've done on reactive transport of melt in the upper mantle and lower crust, there are fantastic field areas where active, ongoing mineral carbonation and hydration can be observed, and the physical mechanisms that control key processes are not well understood. We are focusing on understanding processes in natural systems, particularly “reaction driven cracking”, with relevance to engineered geological capture and storage of CO2, stimulation of geothermal reservoirs, in situ mining, and extraction of hydrocarbon resources from tight formations.
For decades, my primary research interest has been in the genesis and evolution of the Earth's crust in the ocean basins, in arcs, and in continents. I approach this topic from the perspective that reactions between melt and rock during transport through the upper mantle are as important as melting, mixing, and crystal fractionation processes in producing different crustal bulk compositions in different tectonic settings. I’ve been fascinated by the stark compositional difference between oceanic and continental crust, and in my research I have gravitated toward end-member examples of magmatic processes: oceanic spreading ridges, and subduction-related volcanic arcs such as the Aleutians where the composition of average lavas and exposed plutonic rocks closely resembles continental crust. In an ongoing effort, I've tried to develop a general theory that explains how reactive melt transport varies along different geothermal gradients, with, 1. mineral dissolution and focusing of flow into high permeability channels in hot, upwelling mantle, 2. diffuse flow where there is a low melt flux into conductively cooled, shallow mantle, and, 3. hydrofracture where high melt flux and crystallization due to cooling clog porosity, leading to ponding of magma and increasing melt pressure. I’ve also become very interested in gravitational instabilities that can remove dense lithologies from the base of the crust, and transport buoyant subducted sediments and felsic igneous rocks from subduction zones back into the crust, and I hope to pursue investigations of metasediments in lower crustal granulite terrains: how do they get down there?
In studying layered intrusions and lower oceanic crust, I’ve tried to understand a few of the many possible mechanisms for forming both compositional and modal layering in gabbros, via injection of layer parallel sills, and via sudden changes in pressure that can modify the assemblage of minerals precipitating from a cooling magma. This research led to general ideas about formation of oceanic crust, via a “sheeted sills” mechanism in which the lower crust crystallizes from many small sills, injected at depths throughout the crust. This end-member process stands in contrast to the “gabbro glacier” hypothesis, in which all oceanic plutonic rocks crystallize in a single, shallow melt lens and undergo ductile flow downward and outward to “fill” the lower crust. A related issue is the mode of cooling of the oceanic lower crust; via conduction with limited, diffuse fluid flow, or via rapid, focused hydrothermal convection. Trying to quantify and constrain these hypotheses, and to determine which processes predominate in different tectonic settings, has motivated a lot of research over the past 15 years.
I've been very fortunate to work with a large number of tolerant geophysicists (Jack Whitehead, Einat Aharonov, Steve Holbrook, Marc Spiegelman, Greg Hirth, Jun Korenaga, Matthew Jull, and others) who have led me into the world of geodynamics. I am grateful to them all, particularly Greg Hirth, with whom I have been able to pursue interdisciplinary studies.
Finally, not that long ago, I was a founding partner of Dihedral Exploration, mineral exploration consultants specializing in field work requiring technical climbing skills. Searching for ore deposits took me to British Columbia, Alaska and Greenland. I've recently started teaching a new course, Earth Resources for Sustainable Development, which covers some of that field, as well as energy resources, water, soil and fertilizer. I’ve been writing general articles and giving public presentations on this topic
The case for reactive crystallization at mid-ocean ridges, Journal of Petrology (Submitted)
Reaction-driven cracking during retrograde metamorphism: Olivine hydration and carbonation, Earth and Planetary Science Letters, Volume: 345–348 p.: p. 81 (2012)
Coexisting serpentine and quartz from carbonate-bearing serpentinized peridotite in the Samail Ophiolite, Oman, Mineralogy and Petrology, Volume: 164 (2012)
Differentiation of the continental crust by relamination, Earth and Planetary Science Letters 06/02/2011, Volume: 307 p.: 15 (2011)
Rates and Mechanisms of Mineral Carbonation in Peridotite: Natural Processes and Recipes for Enhanced, in situ CO2 Capture and Storage, Annual Review of Earth and Planetary Sciences, Volume: 39 p.: 93 (2011)
Diapirs as the source of the sediment signature in arc lavas, Nature Geoscience, Volume: 4 (2011)
Rates and mechanisms of peridotite carbonation: preliminary data from Oman, recipes for enhanced, in situ CO2 capture & storage, and avenues for continued research, Annual Reviews of Earth & Planetary Science (2010)
Composition and genesis of depleted mantle peridotites from the Wadi Tayin massif, Oman ophiolite. Major and trace element geochemistry, and Os isotope and PGE systematics, Journal of Petrology, Volume: 51 (2010)
Investigation of the strength contrast at the Moho: A case study from the Oman Ophiolite, Geology, Volume: 38 (2010)
Microstructural and rheological evolution of a mantle shear zone, Journal of Petrology, Volume: 51 (2010)
Trapped melt in the Josephine peridotite: Implications for permeability and melt extraction in the upper mantle, Journal of Petrology, Volume: 51 (2010)
A felsic end to Bushveld differentiation, Journal of Petrology, Volume: 51 (2010)